全文获取类型
收费全文 | 2136篇 |
免费 | 419篇 |
国内免费 | 209篇 |
专业分类
化学 | 1455篇 |
晶体学 | 27篇 |
力学 | 110篇 |
综合类 | 19篇 |
数学 | 291篇 |
物理学 | 862篇 |
出版年
2024年 | 1篇 |
2023年 | 52篇 |
2022年 | 52篇 |
2021年 | 94篇 |
2020年 | 105篇 |
2019年 | 83篇 |
2018年 | 71篇 |
2017年 | 81篇 |
2016年 | 132篇 |
2015年 | 125篇 |
2014年 | 138篇 |
2013年 | 172篇 |
2012年 | 218篇 |
2011年 | 231篇 |
2010年 | 146篇 |
2009年 | 150篇 |
2008年 | 128篇 |
2007年 | 112篇 |
2006年 | 102篇 |
2005年 | 89篇 |
2004年 | 68篇 |
2003年 | 56篇 |
2002年 | 51篇 |
2001年 | 45篇 |
2000年 | 29篇 |
1999年 | 28篇 |
1998年 | 21篇 |
1997年 | 25篇 |
1996年 | 25篇 |
1995年 | 22篇 |
1994年 | 19篇 |
1993年 | 13篇 |
1992年 | 14篇 |
1991年 | 15篇 |
1990年 | 19篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1974年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2764条查询结果,搜索用时 359 毫秒
91.
92.
93.
Chang Su Jin‐Song Gong Jin‐Peng Ye Ji‐Meng He Rui‐Yi Li Min Jiang Yan Geng Yan Zhang Jing‐Hua Chen Zheng‐Hong Xu Jin‐Song Shi 《Macromolecular bioscience》2020,20(9)
Keratin is widely recognized as a high‐quality renewable protein resource for biomedical applications. Despite their extensive existence, keratin resources such as feathers, wool, and hair exhibit high stability and mechanical properties because of their high disulfide bond content. Consequently, keratin extraction is challenging and its application is greatly hindered. In this work, a biological extraction strategy is proposed for the preparation of bioactive keratin and the fabrication of self‐assembled keratin hydrogels (KHs). Based on moderate and controlled hydrolysis by keratinase, keratin with a high molecular weight of approximately 45 and 28 kDa that retain its intrinsic bioactivities is obtained. The keratin products show excellent ability to promote cell growth and migration and are conferred with significant antioxidant ability because of their intrinsically high cysteine content. In addition, without the presence of any cross‐linking agent, the extracted keratin can self‐assemble into injectable hydrogels. The KHs exhibit a porous network structure and 3D culture ability, showing potential in promoting wound healing. This enzyme‐driven keratin extraction strategy opens up a new approach for the preparation of keratin that can self‐assemble into injectable hydrogels for biomedical engineering. 相似文献
94.
Li Jilin Feng Junning Li Yongquan Dong Fuyuan Geng Guihong 《Journal of Thermal Analysis and Calorimetry》2020,142(4):1429-1435
Journal of Thermal Analysis and Calorimetry - Mg–RE alloys are high-strength magnesium alloys with great application potential. The solidification pathways and microstructure formation of... 相似文献
95.
拾取指定长度的半导体性碳纳米管对大规模制造碳纳米管场效应管具有重要意义.本文提出了一种利用原子力显微镜探针和钨针对碳纳米管进行可控长度拾取的方法并进行了碳纳米管导电性分析.在扫描电子显微镜下搭建微纳操作系统,针对切割操作过程中原子力显微镜探针、钨针和碳纳米管的接触情况进行了力学建模和拾取长度误差分析.建立了单根金属性碳纳米管、单根半导体性碳纳米管及碳纳米管束与钨针接触的电路模型,推导了接入不同性质碳纳米管后电路的电流电压特性方程.使用原子力显微镜探针对碳纳米管的空间位姿进行调整,控制钨针对碳纳米管上目标位置进行通电切割,同时获取切割电路中的电流电压数据.实验结果表明,本文提出的方法能够有效控制所拾取碳纳米管的长度,增加碳纳米管与原子力显微镜探针的水平接触长度能够减小碳纳米管形变导致的拾取长度误差,建立的电流电压特性方程能够用于分析碳纳米管的导电性. 相似文献
96.
Synthesis of ethylene/vinyl ester copolymers with pendent linear branches via ring‐opening metathesis polymerization of fatty acid‐derived cyclooctenes 下载免费PDF全文
Yuchen Feng Suyun Jie Bo‐Geng Li 《Journal of polymer science. Part A, Polymer chemistry》2017,55(13):2211-2220
Fatty acid‐derived cyclooctenes, including n‐hexanoic acid ( M1 ), n‐octanoic acid ( M2 ), lauric acid ( M3 ), and palmitic acid ( M4 ), were prepared as monomers and polymerized by ring‐opening metathesis polymerization (ROMP) using Grubbs second‐generation catalyst ( G2 ). In all the cases, the regio‐irregular unsaturated polymers with pendent linear branches were obtained, which could be saturated by chemical hydrogenation with TSH/TPA in high conversion, yielding ethylene/vinyl ester copolymers with pendent linear branches on precisely every eighth backbone carbon. Both unsaturated and saturated polymers were amorphous, and their structures were characterized by FTIR, 1H and 13C NMR spectra, and elemental analysis. Differential scanning calorimetry (DSC) and thermo‐gravimetric analysis (TGA) were used to study their thermal properties. The chain length of branches greatly affected the thermal properties of polymers. After hydrogenation, the thermal degradation stability of polymers was relatively improved. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2211–2220 相似文献
97.
Difference systems of sets (DSS) are combinatorial configurations that arise in connection with code synchronization. This paper proposes a new method to construct DSSs, which uses known DSSs to partition some of the cosets of Zv relative to subgroup of order k, where v = km is a composite number. As applications, we obtain some new optimal DSSs. 相似文献
98.
This paper continues the analysis on the Lengyel–Epstein reaction- diffusion system of the chlorite-iodide-malonic acid-starch (CIMA) reaction for the rich Turing structures. The steady state structures, especially the double bifurcation one, and their stability and multiplicity are studied by the use of Lyapunov–Schmidt reduction technique and singularity theory. Numerical simulations are presented to support our theoretical studies. The results show that the richer stationary Turing patterns heavily rely both on the size of the reactor and on the effective diffusion rate in the CIMA reaction. 相似文献
99.
Low-temperature combustion synthesis of CuCr2O4 spinel powder for spectrally selective paints 总被引:1,自引:0,他引:1
Geng Qingfen Zhao Xin Gao Xianghu Yang Shengrong Liu Gang 《Journal of Sol-Gel Science and Technology》2012,61(1):281-288
CuCr2O4 spinel powder with high quality black hue, investigated as solar-absorbing pigment for spectrally selective paint, was synthesized
by an environmental friendly sol–gel combustion process using citric acid as the fuel and metal nitrates as oxidizers. Single-phase
CuCr2O4 spinel crystals were obtained after heat treatment of the as-burnt powder at a low temperature (600 °C) and the average crystallite
size of the CuCr2O4 powders increased with the calcining temperature. Morphological analysis of powders calcined at various temperatures was
done by field emission scanning electron microscopy. CuCr2O4 powder calcined at 700 °C was chosen as pigment to fabricate thickness sensitive spectrally selective paint coatings by simple
spray-coating technique. For the sake of comparison, the as-burnt powder composed of mixed metal oxides (i.e., CuO and Cr2O3) was also used as pigment. The results reveal that the spinel CuCr2O4 based paint coatings exhibit much higher spectral selectivity (α
s = 0.88–0.91, ε
100 = 0.27–0.35) which is depending on the coating thicknesses than that of coatings using as-burnt powder as pigment (α
s = 0.83–0.88, ε
100 = 0.60–0.66). The CuCr2O4-based paint coatings showed no visible degradation after 600 h of condensation test and the performance criterion value is
0.04, indicating that the coatings have excellent long term stability. 相似文献
100.